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Untempered martensite is a strong, hard, brittle material. The stronger and harder it is, the more brittle it is. The strength and hardness is a due to elastic strain within the martensite, which is a result of too many carbon atoms being in the spaces between the iron atoms in the martensite.
As a result of the quenching, the face-centered cubic austenite transforms to a highly strained body-centered tetragonal form called martensite that is supersaturated with carbon. The shear deformations that result produce a large number of dislocations, which is a primary strengthening mechanism of steels.
The alpha phase is called ferrite. Ferrite is a common constituent in steels and has a Body Centred Cubic (BCC) structure [which is less densely packed than FCC]. Fe3C is called cementite and lastly (for us), the “eutectic like” mixture of alpha+cementite is called pearlite.
Body-centered cubic (bcc) packings of atoms tend to be most stable near the melting point because the atoms have room to vibrate (important at high temperatures): face-centered cubic (fcc) crystals are common among metals at low temperatures because the atoms pack well.১২ এপ্রিল, ১৯৯৬
Table 1: Crystal Structure for some Metals (at room temperature)
Aluminum | FCC | FCC |
---|---|---|
Cadmium | HCP | BCC |
Iron | BCC | HCP |
Lead | FCC | HCP |
Magnesium | HCP |
Yes the APF is important, the atomic packing factor, that is the reason FCC has more slip systems, because of the way the atoms are arranged in the crystal. Thus FCC metals deform easier than BCC metals and thus they are more ductile. BCC metals are infact stronger than FCC metals. HCP metals are the most brittle.৪ মার্চ, ২০০৯
If the unit cell also contains an identical component in the center of the cube, then it is body-centered cubic (bcc) (part (b) in Figure 12.5). If there are components in the center of each face in addition to those at the corners of the cube, then the unit cell is face-centered cubic (fcc) (part (c) in Figure 12.5).১২ আগস্ট, ২০২০
Martensite
The ferrite is soft and ductile, whereas the cementite is hard and brittle. The steel has an increased mechanical strength because of both the presence of the two phases and because of their pearlite microstructure, however this comes at the cost of reduced ductility.
Phases in Fe–C Phase Diagram • Fe3C (iron carbide or cementite) It is an intermetallic compound between iron and carbon. It contains 6.67 % carbon and is hard and brittle. This intermetallic compound is a metastablephase and it remains as a compound indefinitely at room temperature.
Manganese removes oxygen and sulfur when iron ore (an iron and oxygen compound) is converted into iron. It also is an essential alloy that helps convert iron into steel. As an alloy it decreases the brittleness of steel and imparts strength.
Silicon, 14Si28.0855 Silicon increases strength and hardness but to a lesser extent than manganese. It is one of the principal deoxidizers used in the making of steels to improve soundness, i.e. to be free from defects, decays or damages. Silicon is present in all steels to a certain extent.
High-strength austenitic stainless steels can be produced by replacing carbon with nitrogen. Nitrogen has greater solid-solubility than carbon, is a strong austenite stabilizer, potent interstitial solid-solution strengthener, and improves pitting corrosion resistance.৩০ মার্চ, ১৯৯৬
Sulphur improves machinability but lowers transverse ductility and notched impact toughness and has little effects on the longitudinal mechanical properties. Free cutting steels have sulphur added to improve machinability, usually up to a maximum of 0.35%.১৩ অক্টোবর, ২০১৫
(also called heat resistance), the ability of steel, upon heating to red heat, to retain the great hardness and durability obtained through heat treatment. For example, high-speed steel retains Rockwell C hardness of up to 60 at 620°-650°C. Hard alloys have the highest level of red-hardness (up to 900°C).
Chromium (Cr): Chromium is added to steel to increase resistance to oxidation. This resistance increases as more chromium is added. Nickel (Ni): Nickel is added in large amounts, over about 8%, to high Chromium stainless steels to form the most important class of corrosion and heat resisting steels.
Desulfurization of steel by injection of active agents Injection of desulfurizing agents to a molten steel is the most effective method of sulfur removal. Injection methods usually combine supply of a disperse desulfurizing agent (powder) with stirring by argon blowing.৩১ মে, ২০১২
The method entails melting a prepared slag in a separate furnace and tapping into the ladle before steel tapping. The induction furnace steel is then tapped onto this slag. The rapid mixing of the slag with the steel during tapping completes the removal of phosphorus even while tapping is going on.২ ফেব, ২০১৭
Slag is a multi-component system and in steelmaking it consists of acidic oxides such as SiO2 and P2O5, and basic oxides such as FeO, CaO, MgO etc. In some slags Al2O3 is also present. In the last lecture we noted that acidic oxides are network formers, whereas basic oxides are network breakers.
Desulfurization or desulphurisation is a chemical process for the removal of sulfur from a material. This involves either the removal of sulfur from a molecule (e.g. A=S → A:) or the removal of sulfur compounds from a mixture such as oil refinery streams.
Removal of sulphur from hot metal is called desulphurization of hot metal. Sulphur is a desirable element in steel when good machinability is required from the steel product. It forms undesirable sulphides which promotes granular weakness and cracks in steel during solidification. …১৬ অক্টোবর, ২০১৩
The purpose of removing the sulfur is to reduce the SO2 emissions. The HDS process involves catalytic treatment with hydrogen to convert the various sulfur compounds present to hydrogen sulfide.২৫ মে, ২০১৬
Flue gas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide (SO2) from exhaust flue gases of fossil-fuel power plants, as well as from the emissions of other sulfur oxide emitting processes.
Question Types There should be three types of questions in a focus group discussion: Probe questions: these introduce participants to the discussion topic and make them feel more comfortable sharing their opinion with the group. Follow-up questions: delve further into the discussion topic and the participants’ opinions.১১ সেপ্টেম্বর, ২০১৭
Wet scrubbing using a slurry of alkaline sorbent, usually limestone or lime, or seawater to scrub gases; Spray-dry scrubbing using similar sorbent slurries; Dry sorbent injection systems that introduce powdered hydrated lime (or other sorbent material) into exhaust ducts to eliminate SO2 and SO3 from process emissions.
It involves mixing of crushed limestone/lime with water to form a slurry and spraying it into the sulphur containing flue gases. The sorbent reacts with SO2 and forms an aqueous slurry of calcium sulphite. About 90% SO2 removal can be achieved.১০ জুন, ২০১৫