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Pauli’s Exclusion Principle states that no two electrons in the same atom can have identical values for all four of their quantum numbers. In other words, (1) no more than two electrons can occupy the same orbital and (2) two electrons in the same orbital must have opposite spins (Figure 46(i) and (ii)).
The Pauli exclusion principle helps explain a wide variety of physical phenomena. One particularly important consequence of the principle is the elaborate electron shell structure of atoms and the way atoms share electrons, explaining the variety of chemical elements and their chemical combinations.
The Aufbau principle states that electrons fill lower-energy atomic orbitals before filling higher-energy ones (Aufbau is German for “building-up”). By following this rule, we can predict the electron configurations for atoms or ions.
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why is it so as it violates aufbau principle? Answer: Electronic Configuration of Lanthanides: as the 4f and 5d electrons are so close in energy it is not possible to decide whether the electron has entered the 5d or 4f orbital.
Hence Actinium violates the Aufbau’s Principle. According to the Aufbau principle, the orbital with the lower energy level must be filled first completely, before moving on to the next orbital. 4s orbital is a lower energy orbital as compared to 3d.
Orbitals fill in order of energy. So 5D fills before 4F in some cases simply because the 5D energy levels are lower than the 4F levels for some. This does not occur for all the lanthanides.
The order of the electron orbital energy levels, starting from least to greatest, is as follows: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p. Since electrons all have the same charge, they stay as far away as possible because of repulsion.
The 2 s and 2 p orbitals differ in shape, number, and energy. A 2 s orbital is spherical, and there is only one of them. A 2 p orbital is dumbbell-shaped, and there are three of them oriented on the x, y, and z axes. The 2 p orbitals have higher energy than the 2 s orbital.